June 16, 2021

Download Ebook Free Direct Synthesis Of Metal Complexes

Direct Synthesis of Coordination and Organometallic Compounds

Direct Synthesis of Coordination and Organometallic Compounds
Author : A.D. Garnovskii,B.I. Kharisov
Publisher : Elsevier
Release Date : 1999-08-13
Category : Science
Total pages :244
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This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

Direct Synthesis of Metal Complexes

Direct Synthesis of Metal Complexes
Author : B.I. Kharisov
Publisher : Elsevier
Release Date : 2018-04-19
Category : Science
Total pages :468
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Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Carbonylation

Carbonylation
Author : H.M. Colquhoun,D.J. Thompson,M.V. Twigg
Publisher : Springer Science & Business Media
Release Date : 2013-06-29
Category : Science
Total pages :296
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Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

The Development of a General Direct Synthesis of Metallocarboranes

The Development of a General Direct Synthesis of Metallocarboranes
Author : William John Evans
Publisher : Unknown
Release Date : 1973
Category : Boranes
Total pages :364
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Russian Journal of Coordination Chemistry

Russian Journal of Coordination Chemistry
Author : Anonim
Publisher : Unknown
Release Date : 1999
Category : Coordination compounds
Total pages :129
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The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals

The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals
Author : Billy Thomas Upchurch
Publisher : Unknown
Release Date : 1967
Category :
Total pages :114
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Spectral Methods in Transition Metal Complexes

Spectral Methods in Transition Metal Complexes
Author : K. Sridharan
Publisher : Elsevier
Release Date : 2016-02-13
Category : Science
Total pages :202
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Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes. Provides readers with a single reference on metal complexes and coordination compounds Contains more than 100 figures, tables, and illustrations to aid in the retention of key concepts Authored by a scientist with nearly 40 years of experience in research and instruction

Russian Chemical Reviews

Russian Chemical Reviews
Author : Anonim
Publisher : Unknown
Release Date : 2005
Category : Chemistry
Total pages :129
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Transition metal Organometallics In Organic Synthesis

Transition metal Organometallics In Organic Synthesis
Author : Howard Alper
Publisher : Academic Press
Release Date : 2012-12-02
Category : Science
Total pages :270
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Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.

The Coordination Chemistry of D- and F-block Metal Complexes of 1,2-benzenediolenes

The Coordination Chemistry of D- and F-block Metal Complexes of 1,2-benzenediolenes
Author : Stephen Robert Sofen
Publisher : Unknown
Release Date : 1979
Category :
Total pages :276
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Book of Abstracts

Book of Abstracts
Author : American Chemical Society. Meeting,American Chemical Society
Publisher : Unknown
Release Date : 1976
Category : Chemistry
Total pages :129
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INIS Atomindex

INIS Atomindex
Author : Anonim
Publisher : Unknown
Release Date : 1985
Category : Nuclear energy
Total pages :129
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Patai's Guide to the Chemistry of Functional Groups

Patai's Guide to the Chemistry of Functional Groups
Author : Saul Patai
Publisher : Unknown
Release Date : 1989-05-05
Category : Science
Total pages :455
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In this handy reference guide and index to the volumes in the The Chemistry of Functional Groups series, all volumes are indexed and cross-referenced (according to related and complementary chapters). Users of the series will find this volume indispensable for finding information quickly and easily.

Indian Journal of Chemistry

Indian Journal of Chemistry
Author : Anonim
Publisher : Unknown
Release Date : 2006
Category : Chemistry
Total pages :129
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